COVALENT ORGANIC FRAMEWORKS (Record no. 70279)
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| 000 -LEADER | |
|---|---|
| fixed length control field | 06717cam a2200577M 4500 |
| 001 - CONTROL NUMBER | |
| control field | 9781003004691 |
| 005 - DATE AND TIME OF LATEST TRANSACTION | |
| control field | 20220711212045.0 |
| 008 - FIXED-LENGTH DATA ELEMENTS--GENERAL INFORMATION | |
| fixed length control field | 200103s2019 xx o 000 0 eng d |
| 020 ## - INTERNATIONAL STANDARD BOOK NUMBER | |
| ISBN | 9781000758436 |
| -- | (electronic bk.) |
| 020 ## - INTERNATIONAL STANDARD BOOK NUMBER | |
| ISBN | 1000758435 |
| -- | (electronic bk.) |
| 020 ## - INTERNATIONAL STANDARD BOOK NUMBER | |
| ISBN | 9781003004691 |
| -- | (electronic bk.) |
| 020 ## - INTERNATIONAL STANDARD BOOK NUMBER | |
| ISBN | 1003004695 |
| -- | (electronic bk.) |
| 020 ## - INTERNATIONAL STANDARD BOOK NUMBER | |
| ISBN | 9781000759174 |
| -- | (electronic bk. : EPUB) |
| 020 ## - INTERNATIONAL STANDARD BOOK NUMBER | |
| ISBN | 1000759172 |
| -- | (electronic bk. : EPUB) |
| 020 ## - INTERNATIONAL STANDARD BOOK NUMBER | |
| ISBN | 9781000758801 |
| -- | (electronic bk. : Mobipocket) |
| 020 ## - INTERNATIONAL STANDARD BOOK NUMBER | |
| ISBN | 100075880X |
| -- | (electronic bk. : Mobipocket) |
| 082 04 - CLASSIFICATION NUMBER | |
| Call Number | 378.76935 |
| 100 1# - AUTHOR NAME | |
| Author | Nagai, Atsushi. |
| 245 10 - TITLE STATEMENT | |
| Title | COVALENT ORGANIC FRAMEWORKS |
| 260 ## - PUBLICATION, DISTRIBUTION, ETC. (IMPRINT) | |
| Place of publication | [S.l.] : |
| Publisher | PAN STANFORD PUBLISHING, |
| Year of publication | 2019. |
| 300 ## - PHYSICAL DESCRIPTION | |
| Number of Pages | 1 online resource |
| 520 ## - SUMMARY, ETC. | |
| Summary, etc | Rational synthesis of extended arrays of organic matter in bulk, solution, crystals, and thin films has always been a paramount goal of chemistry. The classical synthetic tools to obtain long-range regularity are, however, limited to noncovalent interactions, which usually yield structurally more random products. Hence, a combination of porosity and regularity in organic covalently bonded materials requires not only the design of molecular building blocks that allow for growth into a nonperturbed, regular geometry but also a condensation mechanism that progresses under reversible, thermodynamic, self-optimizing conditions. Covalent organic frameworks (COFs), a variety of 2D crystalline porous materials composed of light elements, resemble an sp2-carbon-based graphene sheet but have a different molecular skeleton formed by orderly linkage of building blocks to constitute a flat organic sheet. COFs have attracted considerable attention in the past decade because of their versatile applications in gas storage and separation, catalysis, sensing, drug delivery, and optoelectronic materials development. Compared to other porous materials, COFs allow for atomically precise control of their architectures by changing the structure of their building blocks, whereby the shapes and sizes of their pores can be well-tuned. Covalent Organic Frameworks is a compilation of different topics in COF research, from COF design and synthesis, crystallization, and structural linkages to the theory of gas sorption and various applications of COFs, such as heterogeneous catalysts, energy storage (e.g., semiconductors and batteries), and biomedicine. This handbook will appeal to anyone interested in nanotechnology and new materials of gas adsorption and storage, heterogeneous catalysts, electronic devices, and biomedical devices. |
| 505 0# - FORMATTED CONTENTS NOTE | |
| Remark 2 | Cover -- Half Title -- Title Page -- Copyright Page -- Table of Contents -- Preface -- 1: Design and Synthesis: Covalent Organic Frameworks -- 1.1 Introduction -- 1.2 Design and Synthesis -- 1.2.1 COF Synthesis in the Dynamic Covalent Chemistry Concept -- 1.2.2 Dynamic Linkages of Building Blocks -- 1.2.3 Topology and Geometry of 2D Porous Materials Containing COFs -- 1.3 Synthetic Methods of COFs -- 1.3.1 Solvothermal Synthesis -- 1.3.2 Ionothermal Synthesis -- 1.3.3 Microwave Synthesis -- 1.3.4 Mechanochemical Synthesis -- 1.3.5 Room-Temperature Synthesis |
| 505 8# - FORMATTED CONTENTS NOTE | |
| Remark 2 | 2: Crystallization and Structural Linkages of COFs -- 2.1 b-O Linkages -- 2.1.1 Boroxine-Linked COFs -- 2.1.2 Boronic Ester (Dioxaborole)-Linked COFs -- 2.1.3 Spiroborate-Linked COFs -- 2.1.4 Borazine-Linked COFs -- 2.2 Imine Linkages -- 2.3 Hydrazone Linkages -- 2.4 Azine Linkages -- 2.5 Squaraine Linkages -- 2.6 Imide Linkages -- 2.7 Phenazine Linkages -- 2.8 Triazine Linkages -- 2.9 Multihetero Linkages in One COF Skeleton -- 2.10 Perspectives and Challenges -- 3: Gas Adsorption and Storage of COFs -- 3.1 Gas Sorption -- 3.2 Physical and Chemical Adsorption -- 3.3 Brunauer-Emmett-Teller Theory |
| 505 8# - FORMATTED CONTENTS NOTE | |
| Remark 2 | 3.4 Hydrogen Gas Storage -- 3.5 Methane Gas Storage -- 3.6 Carbon Dioxide Gas Storage -- 3.7 Membrane Separation of COFs -- 3.7.1 Key Properties of COFs for Membrane Separation -- 3.7.2 Fabrication of COF-Based Membranes -- 3.7.2.1 Design principles -- 3.7.2.2 Blending -- 3.7.2.3 In situ growth -- 3.7.2.4 Layer-by-layer stacking -- 3.7.2.5 Interfacial polymerization -- 3.7.3 Gas Separation of COF-Based Membranes -- 3.8 Outlook and Conclusions -- 4: Heterogeneous Catalytic Application of COFs -- 4.1 Heterogeneous Catalysts of COFs for C-C Bond Coupling Reactions -- 4.1.1 Suzuki-Miyaura Reaction |
| 505 8# - FORMATTED CONTENTS NOTE | |
| Remark 2 | 4.1.2 Heck, Sonogashira, and Silane-Based Cross-Coupling Reactions -- 4.2 Chiral Heterogeneous Catalysts of COFs for Asymmetric C-C Bond Coupling Reactions -- 4.3 Heterogeneous Bimetallic or Bifunctional Catalysts of COFs -- 4.4 Heterogeneous Photo- and Electrocatalysts of COFs -- 4.5 Heterogeneous Catalysts of 3D COFs -- 4.6 Conclusions and Outlook -- 5: Energy Storage Applications of 2D COFs -- 5.1 2D COFs for Optoelectronics and Energy Storage -- 5.2 Semiconducting and Photoconducting 2D COFs -- 5.3 P-Type Semiconducting 2D COFs -- 5.4 N-Type Semiconducting 2D COFs |
| 505 8# - FORMATTED CONTENTS NOTE | |
| Remark 2 | 5.5 Ambipolar Semiconducting 2D COFs -- 5.6 Lithium-Ion Batteries Using 2D COFs as Electrodes -- 5.6.1 Battery Cathode Application -- 5.6.2 Battery Anode Application -- 5.7 Summary and Perspective -- 6: Biomedical Applications of COFs -- 6.1 Introduction of Biomedical Application -- 6.2 COF Properties of Biomedical Applications -- 6.3 Biomedical COF Applications -- 6.3.1 Drug Delivery -- 6.3.2 Photothermal and Photodynamic Therapy -- 6.4 Biosensing and Bioimaging -- 6.5 Other Biomedical Applications -- 6.6 Conclusions of Biomedical Applications -- Index |
| 650 #0 - SUBJECT ADDED ENTRY--SUBJECT 1 | |
| General subdivision | Absorption and adsorption. |
| 856 40 - ELECTRONIC LOCATION AND ACCESS | |
| Uniform Resource Identifier | https://www.taylorfrancis.com/books/9781003004691 |
| 856 42 - ELECTRONIC LOCATION AND ACCESS | |
| Uniform Resource Identifier | http://www.oclc.org/content/dam/oclc/forms/terms/vbrl-201703.pdf |
| 942 ## - ADDED ENTRY ELEMENTS (KOHA) | |
| Koha item type | eBooks |
| 588 ## - | |
| -- | OCLC-licensed vendor bibliographic record. |
| 650 #7 - SUBJECT ADDED ENTRY--SUBJECT 1 | |
| -- | SCIENCE / Chemistry / General |
| 650 #7 - SUBJECT ADDED ENTRY--SUBJECT 1 | |
| -- | SCIENCE / Chemistry / Physical & Theoretical |
| 650 #7 - SUBJECT ADDED ENTRY--SUBJECT 1 | |
| -- | SCIENCE / Chemistry / Industrial & Technical |
| 650 #0 - SUBJECT ADDED ENTRY--SUBJECT 1 | |
| -- | Carbon dioxide |
| 650 #0 - SUBJECT ADDED ENTRY--SUBJECT 1 | |
| -- | Greenhouse effect, Atmospheric. |
| 650 #0 - SUBJECT ADDED ENTRY--SUBJECT 1 | |
| -- | Schiff reaction. |
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