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Molecular thermodynamics of electrolyte solutions [electronic resource] / by Lloyd L. Lee.

By: Lee, Lloyd L.
Material type: materialTypeLabelBookPublisher: Singapore : World Scientific, 2021Edition: 2nd ed.Description: 1 online resource (xv, 278 p.).ISBN: 9789811233005.Subject(s): Electrolytes -- Thermal properties | Electrolyte solutions | Molecular dynamicsGenre/Form: Electronic books.DDC classification: 621.4021 Online resources: Access to full text is restricted to subscribers.
Contents:
Introduction -- Solution thermodynamics of electrolytes -- Basic electrostatics -- The Debye-Hückel theory -- Pitzer's formulation for electrolytes -- The statistical mechanics of electrolytes -- Ions as charged hard spheres: The mean spherical approach -- The Mcmillan-Mayer and Lewis-Randall scales -- Multi-solvent electrolyte solutions : setchenov's salting-out principle -- Ionic distributions : an integral equation approach -- The electric double layers -- Application : absorption refrigeration with electrolytes -- Application : amine solutions in acid gas treating -- Appendices.
Summary: "Electrolytes and salt solutions are ubiquitous in chemical industry, biology and nature. This unique compendium introduces the elements of the solution properties of ionic mixtures. In addition, it also serves as a bridge to the modern researches into the molecular aspects of uniform and non-uniform charged systems. Notable subjects include the Debye-Hückel limit, Pitzer's formulation, Setchenov salting-out, and McMillan-Mayer scale. Two new chapters on industrial applications - natural gas treating, and absorption refrigeration, are added to make the book current and relevant. This textbook is eminently suitable for undergraduate and graduate students. For practicing engineers without a background in salt solutions, this introductory volume can also be used as a self-study"--Publisher's website.
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Includes bibliographical references and index.

Introduction -- Solution thermodynamics of electrolytes -- Basic electrostatics -- The Debye-Hückel theory -- Pitzer's formulation for electrolytes -- The statistical mechanics of electrolytes -- Ions as charged hard spheres: The mean spherical approach -- The Mcmillan-Mayer and Lewis-Randall scales -- Multi-solvent electrolyte solutions : setchenov's salting-out principle -- Ionic distributions : an integral equation approach -- The electric double layers -- Application : absorption refrigeration with electrolytes -- Application : amine solutions in acid gas treating -- Appendices.

"Electrolytes and salt solutions are ubiquitous in chemical industry, biology and nature. This unique compendium introduces the elements of the solution properties of ionic mixtures. In addition, it also serves as a bridge to the modern researches into the molecular aspects of uniform and non-uniform charged systems. Notable subjects include the Debye-Hückel limit, Pitzer's formulation, Setchenov salting-out, and McMillan-Mayer scale. Two new chapters on industrial applications - natural gas treating, and absorption refrigeration, are added to make the book current and relevant. This textbook is eminently suitable for undergraduate and graduate students. For practicing engineers without a background in salt solutions, this introductory volume can also be used as a self-study"--Publisher's website.

Mode of access: World Wide Web.

System requirements: Adobe Acrobat Reader.

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