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Surface Modifications and Growth of Titanium Dioxide for Photo-Electrochemical Water Splitting [electronic resource] / by John Alexander.

By: Alexander, John [author.].
Contributor(s): SpringerLink (Online service).
Material type: materialTypeLabelBookSeries: Springer Theses, Recognizing Outstanding Ph.D. Research: Publisher: Cham : Springer International Publishing : Imprint: Springer, 2016Edition: 1st ed. 2016.Description: XLI, 336 p. 216 illus., 196 illus. in color. online resource.Content type: text Media type: computer Carrier type: online resourceISBN: 9783319342290.Subject(s): Materials | Materials—Analysis | Electrochemistry | Nanoscience | Materials Engineering | Characterization and Analytical Technique | Electrochemistry | NanophysicsAdditional physical formats: Printed edition:: No title; Printed edition:: No title; Printed edition:: No titleDDC classification: 620.11 Online resources: Click here to access online
Contents:
Introduction -- Literature Review -- Principles of Photo-electrochemical Cells -- Experimental Methods -- Results: Plasmonic Photocurrent with AuNP-TiO2 -- Electrochemistry of TiO2 – Rutile (110) -- TiO2 Thin Films on Fused Silica -- Epitaxial TiO2 Thin Films on Single Crystal Substrates -- Conclusions.
In: Springer Nature eBookSummary: This outstanding thesis provides a wide-ranging overview of the growth of titanium dioxide thin films and its use in photo-electrochemicals such as water splitting. The context for water splitting is introduced with the theory of semiconductor-liquid junctions, which are dealt with in detail. In particular plasmonic enhancement of TiO2 by the addition of gold nanoparticles is considered in depth, including a thorough and critical review of the literature, which discusses the possible mechanisms that may be at work. Plasmonic enhancement is demonstrated with gold nanoparticles on Nb-doped TiO2. Finally, the use of temperature and pressure to control the phase and morphology of thin films grown by pulsed laser deposition is presented.
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Introduction -- Literature Review -- Principles of Photo-electrochemical Cells -- Experimental Methods -- Results: Plasmonic Photocurrent with AuNP-TiO2 -- Electrochemistry of TiO2 – Rutile (110) -- TiO2 Thin Films on Fused Silica -- Epitaxial TiO2 Thin Films on Single Crystal Substrates -- Conclusions.

This outstanding thesis provides a wide-ranging overview of the growth of titanium dioxide thin films and its use in photo-electrochemicals such as water splitting. The context for water splitting is introduced with the theory of semiconductor-liquid junctions, which are dealt with in detail. In particular plasmonic enhancement of TiO2 by the addition of gold nanoparticles is considered in depth, including a thorough and critical review of the literature, which discusses the possible mechanisms that may be at work. Plasmonic enhancement is demonstrated with gold nanoparticles on Nb-doped TiO2. Finally, the use of temperature and pressure to control the phase and morphology of thin films grown by pulsed laser deposition is presented.

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