| 000 | 08071nam a2200805 i 4500 | ||
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| 001 | 9780750322768 | ||
| 003 | IOP | ||
| 005 | 20230516170215.0 | ||
| 006 | m eo d | ||
| 007 | cr cn |||m|||a | ||
| 008 | 211108s2021 enka fob 000 0 eng d | ||
| 020 |
_a9780750322768 _qebook |
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_a9780750322751 _qmobi |
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| 020 |
_z9780750322744 _qprint |
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| 020 |
_z9780750322775 _qmyPrint |
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| 024 | 7 |
_a10.1088/978-0-7503-2276-8 _2doi |
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| 035 | _a(CaBNVSL)thg00082705 | ||
| 035 | _a(OCoLC)1280155254 | ||
| 040 |
_aCaBNVSL _beng _erda _cCaBNVSL _dCaBNVSL |
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| 050 | 4 |
_aQD564 _b.P486 2021eb |
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_aPNRH _2bicssc |
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| 072 | 7 |
_aSCI013100 _2bisacsh |
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| 082 | 0 | 4 |
_a541.37 _223 |
| 100 | 1 |
_aPetsev, D. N. _q(Dimiter Nikolov), _d1962- _eauthor. _970153 |
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| 245 | 1 | 0 |
_aMolecular theory of electric double layers / _cDimiter N. Petsev, Frank van Swol and Laura J.D. Frink. |
| 264 | 1 |
_aBristol [England] (Temple Circus, Temple Way, Bristol BS1 6HG, UK) : _bIOP Publishing, _c[2021] |
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_a1 online resource (various pagings) : _billustrations (some color). |
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_atext _2rdacontent |
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| 337 |
_aelectronic _2isbdmedia |
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| 338 |
_aonline resource _2rdacarrier |
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| 490 | 1 | _a[IOP release $release] | |
| 490 | 1 | _aIOP ebooks. [2021 collection] | |
| 500 | _a"Version: 202110"--Title page verso. | ||
| 504 | _aIncludes bibliographical references. | ||
| 505 | 0 | _a1. Introduction : a historical overview -- 1.1. Charges and fields -- 1.2. Electrostatics of systems with distributed charges -- 1.3. The concept of electric double layer | |
| 505 | 8 | _apart I. Theory. 2. The origin of charge at interfaces involving electrolyte solutions -- 2.1. Effects of the surface chemical reactions and the charge regulation model -- 2.2. Effects due to physical adsorption -- 2.3. Structural effects on the ionic and solvent concentration at the interface | |
| 505 | 8 | _a3. Continuum models of the electric double layers -- 3.1. The Poisson-Boltzmann equation -- 3.2. Electric double layer models based on the Poisson-Boltzmann equation : exact and approximate solutions -- 3.3. Beyond the Boltzmann distribution : the semiconductor-electrolyte interface -- 3.4. Electrokinetic phenomena -- 3.5. Deficiencies of the continuum approach | |
| 505 | 8 | _a4. Integral equation theory -- 4.1. Background -- 4.2. Percus-Yevick closure -- 4.3. The hypernetted-chain closure -- 4.4. The mean spherical approximation (MSA) -- 4.5. Hard sphere mixtures -- 4.6. The Ornstein-Zernike equations approach to studying electric double layers | |
| 505 | 8 | _a5. Perturbation and mean field theory -- 5.1. Background -- 5.2. Virial expansions -- 5.3. Zwanzig's perturbation theory -- 5.4. Mean field theory | |
| 505 | 8 | _a6. Density functional theory -- 6.1. Density functional theory for electronic structure -- 6.2. Density functional theory for classical fluids | |
| 505 | 8 | _a7. Classical-DFT for electrolyte interfaces -- 7.1. Molecular models of electrolytes -- 7.2. Classical-DFT for point-charge electrolytes -- 7.3. Classical-DFT for finite-size electrolytes -- 7.4. Classical-DFT with correlations -- 7.5. Classical-DFT with cohesive interactions -- 7.6. Classical-DFT for systems with active surfaces -- 7.7. Classical-DFT for water -- 7.8. Classical-DFT for electrokinetic systems | |
| 505 | 8 | _apart II. Structure of a single electric double layer : effects due to surface charge regulation and non-Coulombic interactions. 8. Molecular properties of a single electric double layer -- 8.1. Classical density functional theory model of a single flat electric double layer -- 8.2. Solution structure in an electric double layer with surface charge regulation -- 8.3. Conclusions | |
| 505 | 8 | _a9. Ionic solvation effects and solvent-solvent interactions -- 9.1. Solvation of the potential determining ions -- 9.2. Solvation of the positive non-potential determining ions -- 9.3. Solvation of the negative non-potential determining ions -- 9.4. Effect of the solvent-solvent fluid interactions -- 9.5. Conclusions | |
| 505 | 8 | _a10. Surface solvation and non-Coulombic ion-surface interactions -- 10.1. Solvent-surface interactions. Solvophilic and solvophobic surfaces -- 10.2. Effect of the non-Coulombic interactions between the potential determining ions and the charged wall -- 10.3. Effect of the non-Coulombic positive ions--surface interactions -- 10.4. Effect of the non-Coulombic negative ions--surface interactions -- 10.5. Conclusions | |
| 505 | 8 | _a11. The potential distribution in the electric double layer and its relationship to the fluid charge -- 11.1. The Poisson equation for structured electrolyte solutions -- 11.2. Molecular interpretation of the Helmholtz planes, the Stern-Grahame layer, and the electrokinetic shear plane -- 11.3. Conclusions | |
| 505 | 8 | _a12. Electric double layers containing multivalent ions -- 12.1. Multivalent ion density profiles in the electric double layer -- 12.2. Effect of the non-potential-determining ions valency on the density profiles of the potential determining ions in the electric double layer -- 12.3. Non-Coulombic surface interactions, charge and potential distributions in the Stern-Grahame layer and beyond -- 12.4. Conclusions | |
| 505 | 8 | _a13. Ionic size effects -- 13.1. Ionic size variations and solution density -- 13.2. Conclusions | |
| 505 | 8 | _apart III. Numerical methods. 14. Molecular simulation : methods -- 14.1. Background -- 14.2. Molecular dynamics methods -- 14.3. The potential distribution theorem (PDT) -- 14.4. Simulation routes to the grand potential | |
| 505 | 8 | _a15. Molecular simulation : applications -- 15.1. Background -- 15.2. One-component plasma -- 15.3. Molten salts -- 15.4. Bulk electrolytes | |
| 505 | 8 | _a16. Numerical methods for classical-DFT -- 16.1. Solution methods -- 16.2. Algorithms for constructing phase diagrams. | |
| 520 | 3 | _aThe electrical double layer describes charge and potential distributions that form at the interface between electrolyte solutions and the surface of an object, and they play a fundamental role in chemical and electrochemical behaviour. Colloid science, electrochemistry, material science, and biology are a few examples where such interfaces play a crucial role. The focus of this book is on the application of modern liquid state theories to the properties of electric double layers, where it demonstrates the ability of statistical mechanical approaches, such as the classical density functional theory, to provide insights and details that will enable a better and more quantitative understanding of electric double layers. The book will be essential reading for advanced students and researchers in interfacial science and its numerous applications. | |
| 521 | _aResearchers. | ||
| 530 | _aAlso available in print. | ||
| 538 | _aMode of access: World Wide Web. | ||
| 538 | _aSystem requirements: Adobe Acrobat Reader, EPUB reader, or Kindle reader. | ||
| 545 | _aDr. Dimiter N. Petsev received his PhD in Physical Chemistry from the University of Sofia.Dr Frank van Swol received his PhD in Physical Chemistry from the University of Amsterdam, The Netherlands, where he was supervised by Prof. L.V. Woodcock. Dr. Laura J. Douglas Frink received her PhD in Chemical Engineering from the University of Illinois at Urbana-Champaign in 1995 where she was advised by Frank van Swol and Charles Zukoski. | ||
| 588 | 0 | _aTitle from PDF title page (viewed on November 8, 2021). | |
| 650 | 0 |
_aElectric double layer. _918792 |
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| 650 | 0 |
_aSurface chemistry. _94753 |
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| 650 | 7 |
_aElectrochemistry & magnetochemistry. _2bicssc _970154 |
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| 650 | 7 |
_aMaterials. _2bisacsh _97549 |
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| 700 | 1 |
_aSwol, Frank van, _eauthor. _970155 |
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| 700 | 1 |
_aFrink, Laura J. D., _eauthor. _970156 |
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| 710 | 2 |
_aInstitute of Physics (Great Britain), _epublisher. _911622 |
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| 776 | 0 | 8 |
_iPrint version: _z9780750322744 _z9780750322775 |
| 830 | 0 |
_aIOP (Series). _pRelease 21. _970157 |
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| 830 | 0 |
_aIOP ebooks. _p2021 collection. _970158 |
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| 856 | 4 | 0 | _uhttps://iopscience.iop.org/book/978-0-7503-2276-8 |
| 942 | _cEBK | ||
| 999 |
_c82791 _d82791 |
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